Benjamin Franklin Analysis free essay sample

This letter was written by Benjamin Franklin long before he came president of the United States of America, Benjamin at the time was In the midst of his life. This document Is unique because It was not Intended for the public. The document suggests that Franklin still carried a sense of consciousness and morality, unlike what his critics say. The letter shows that Franklin was undoubtedly a really intelligent person with a sharp way of thinking. Franklin puts every prospect Into effect In this letter; this explains why he was successful In life.The significance of this document comes In the fact that It Is a personal letter rather than a document published for the public. This is extremely important in analyzing Benjamin Franklins personality accurately. Documents that are made for the public usually are written based upon what is accepted by the society, they tend to not include anything that may affect the writers reputation. It is clear that the society at the time In which the letter was written is deferent from todays society In many ways. American society at the time was much more conservative than it is today.Sexual relationships outside of marriage were considered to be immoral and were shunned by the society. Franklin is wary about to having a person to make the mistake of being found of having an illegal relation or begetting an illegitimate child. The former point may a result of his own experience with his legitimate son William. . In his 6th and 7th point, Franklin puts into effect the guilt of ruining a virgin girls life. He furthermore makes It clear that marriage Is the most proper way to fulfill sexual desires.This explains that Franklin soul has emphasis for morals and ethics. The conclusions about Franklins person put forward from this letter could in fact be used to foreshadow the decisions he made in his future, and how he calculated each cession by carefully studying all the negatives and positives. Supporters of Benjamin Franklin regard this letter In contrary with his critics. Supporters may argue that Franklin understood that not everyone was In the right situation to get married. They also argue that the point put out by this was only to be used as a last resort.Benjamin critics rather carry a conflicting opinion. These documents have used as means to demoralize Benjamin Franklin by his enemies. They claim that Benjamin was in fact a warmonger. Regardless of whos view is more accurate, this letter still monstrance Franklins extraordinary intelligence In critical thinking and decision making. Franklin was never content with mere learned argument and syllogism in his campaigns in the press. In 1770, he had written and published three fables teaching the foolishness of punitive measures against the American colonies.These three fables portrayed Franklins stunning use of literature for propaganda purposes. These fables also resembled the oppressive measures taken by Britain through the numerous acts which were seen as a heavy burden by the colonists. Franklin portrays he colonies as the cows, the cat, and the lion, while portraying Britain as the farmer, the eagle, and the mastiff. Consequently in all three fables, the weak overcomes the strong, but only as a result of extreme oppression by the strong. These fables may be have been perceived as an indirect threat to the British in colonial America. The fables were published during a time in which there was increasing tension between the colonists and the British. Franklin at the time was appointed as an agent of several colonies to the crown. His job was to convince the king and the parliament to change their policies towards the American colonies. These fables further ascertain Franklins enormous talent in literature. Writing such precise and explanatory stories in Just a few sentences require a great author, Franklin has proven himself likewise.Franklin attempted to use these fables as political propaganda, as well as to draw support towards the American cause. By getting the English lords and decision makers to view it, Benjamin Franklin wanted to make it clear that treating the American colonies as cash cows would certainly backfire. This document draws its significant mainly due to the foreshadowing of the American Revolution. Not many people would probably have taken this writing seriously when it was first published, but some years later and with the beginning of the American Revolution, people would truly start to admire these fables.The British decision makers in which the fables were inscribed probably have showed little interest, that is clearly shown by the fact they continued to ignore the demands of the American colonies. Perhaps the nature of these fables prompted the British decision makers to further ignore the demands because they saw these fables as a challenge, and they wanted to show that they could face such challenges. Franklins has done an excellent Job in summoning his literary skills for the American cause. The writing of the Three Fables was a symbolic warning to the English administration.Although the fables sounded threatening, the English parliament still didnt react seriously to the Am erican demands. Benjamin writing was an early foreshadowing of the American Revolution. He has shown that he is indeed a true American patriot. Rules by which A Great empire May Be Reduced to a Small One After failing to secure support in England, Franklin resorted to political satire in order to express the colonies grievances. In the sass, even after helping to defeat the Stamp Act and (later) the Townsend Acts, Franklin grew frustrated with the British leaders ignorance of America and condescending attitude toward the colonies.He wrote more essays denouncing British policies towards America. Rules By Which a Great Empire May Be Reduced to a Small One was one of the most known of these essays. The essay was clearly deprecated by the British. Franklin argued that the settlers and their ancestors were the ones who have built and expanded the colonies. Benjamin Franklin has shown that he was a true patriot through this essay. Franklins essay was most likely received by widespread discontent by both the public and the authorities in England.The fact that the writing threatened that British colonies may start breaking away has caused many British nationalists to condemn and refuse Franklins ideas. Even some of the lords who held some sympathy for the American cause pulled out their support after this essay was published. The King has probably received this with even wider discontent. It did not only make a direct threat to the kings authority, but the points within were more of an order than that of a request. That may have further prompted the British authorities to ignore the requests.Franklin also argued that the colonists and their ancestors are the ones who worked hard to bring the colonies to what they were at the time. Most colonials would have agreed with Franklins reasoning. Many of the American born colonists did not see any real connection with Britain. This shows the deepening division that was occurring between the American colonies and Britain at the time. Although the writing shows that Benjamin Franklin would have preferred to prevent violent escalation between Britain and the American colonies, it was clear he put the interest f the American colonies first.Benjamin Franklin has pointed out some great points in the document Rules By Which a Great Empire May Be Reduced to a Small One. His ideas which threatened that British colonies may did not sound appealing to people of Britain. This piece of writing also showed the widening rift between Britain and the American colonies. It was also made clear that Franklin put the interest of the American colonies as a priority. Although he sounded strict in some of his points, He has shown that he indeed does have what it takes to be a great leader.

Electoral College Essays (727 words) - Electoral College

Electoral College The framer's intent of setting up the American Government will never be know for sure, but it is gathered that they preferred a republic over a democracy. In the constitutional convention the drafters had to decide how much power they would entrust with the people of the United States, and how much should be controlled by representatives. They chose to have Congress Make the laws, and congress would be selected directly by the people. But another branch of government, the executive branch, needed a sole president and the framers had to decide how to choose this president. They chose from three main systems: elect the president by congress, the people, or electors. The electoral college system has been in place for over 200 years and Americans are still not sure how it works or if it is the best system. Many Americans feel they go to the polls every year and vote for the president, and in the long run they are in control of the fate of our executive branch. This third system was to have electors that could not be a member of congress vote for the president. The elector system was voted down twice, once as the electors to be chosen by state legislatures, and the other time as the electors to be chosen by direct vote. Finally it was passed under the system of letting state legislature decide how to choose the electors. Another compromise had to be made about how many electors each state would have. This was agreed upon by the electors equaling the total of the states representatives and senators. States went three main routes in choosing electors: the legislative system, where state legislatures choose the electors; a district system, where electors are selected by the people of each congressional district; and the general ticket, or a winner-take-all system, where a popular vote was held in the entire state, and the winner took all electoral votes. Many have tried to reform by making a more uniform system state by state, but the constitution is very clear that it is each state's own decision of how to choose electors. The legislative system eventually failed because of too much bargaining, promises, and payoffs. The district system eventually lost popularity because it encourages third parties. This left the general ticket system as the dominating system. However, the framers originally intended electors to be chosen by the people and then vote for what they thought was best. There are two states that still use the district system, but the remaining 48 states use the general ticket system. Most all states no longer show the electors' names on the ballot. The voter votes for either the president or the party that they wish to hold office. This causes a problem of the unfaithful elector. Electors are expected to ratify the people's choice by voting for candidates winning the popular election. Electors that do not vote for what they are expected to vote for are considered faithless or unfaithful electors. This has not traditionally been a problem in the history of the electoral college but it could possibly be a problem. Less than 1% of electors have ever misrepresented their community. 26 states do not require an elector to vote for what they have pledged to vote for by state law. Although these states are still considered under the general ticket system. Basically the electoral college system works like this today. Every ten years the census figures adjusts how many representatives each state has. This number plus two, representing the two senators, equals how many electors each state has. Also, DC has 3 electors. Then each state has the right to decide how to select these electors. Forty eight states use the general ticket system, two, Maine and Nebraska, use the district system. The general ticket system is suppose to operate as follows. There is a direct vote election held in each state and the winner of the vote is suppose to get all of that states electoral votes. In Maine and Nebraska there is an election held in each congressional district. The winner of every district gets one electoral vote, and the candidate with the most electoral votes gets the remaining two electoral votes. Then all of the votes are counted, and if a candidate gets more than half the votes, he/she becomes the new president. If there is no majority then the election gets thrown into the House of Representatives. There each state is given one vote and they

Wildlife Protection essays

Wildlife Protection essays There are many ways to protect wildlife in our community, the country, and the world. First of all, there are many parks and reserves available for indigenous life to find sanctuary from human expansion. The ecological concerns of water, forest, and wetlands have been achieved through Congress. The Florida Everglades are home to millions of forms of life, most notable the American Alligator. These swampy regions have always been in turmoil and in fear of being used for the ever-expanding human race. Approval for a historic resolution sailed through the House of Representatives but included a host of unrelated projects that could damage the environment elsewhere. The Everglades has been reduced to half its original size by a century of agricultural growth, urban sprawl, and unwise water management. Dikes, levees and dams have fundamentally altered the natural system by draining billions of gallons of water a day out to sea. The best way to alleviate the problem and save the Everglades is to contact Representatives and Senators with the message that Everglade restoration must follow through within the year. The wildlife there is losing land and acreage daily. Everglades restoration must move forward this year. Another concern of many is the refueling of ships at sea. Everyone has seen the devastating effects an oil spill has on an ecosystem. It is probably the most horrible disasters ever brought to earth by the making of men. The best way to be rid of the horrible disaster of oil spills is to only refuel on land. This would greatly reduce the chance of spillage by 100 percent and ensure wildlife habitat protection. ...

Marketing Plan Essay Example | Topics and Well Written Essays - 2000 words

Marketing Plan - Essay Example 95% of ingredients are ordered on the basis of sources to make a product. This means that company has high reliance on farmers for the cultivation of organic ingredients. Perfect potion is not involved in animal testing. Its production department measures safety of both animals as well as humans, even the minerals used in products is exempted from petroleum and silicones products. Perfect portion does not deal with products which are subjected to dyes, coloring agents, paraffin or fragrances However, considering the present condition of the company, its manufacturing cost is increasing rapidly, 20% of the cost is allocated to raw material and if there is any minute error it will be an addition to the cost. To control this it requires an integrated management system. 1.2 Background In accordance with the corporate service manager of perfect portion, this company was established by one man, having one outlet, limited products and manufacturing of these products was done in a garage. It was a very small business. As this business began to grow more stores were opened, wide product varieties, large network and also resulted in many problems. It is a common thinking that as a business grows more problems exists as compared to that of small business. Though company had huge business but it wasn’t managed accordingly. ... Some of these forces affecting the present situation of the company are described below: Micro forces Intermediaries Intermediaries play a key role in controlling the internal and external environment of the company. All depends on the process and management carried out by top level executives. Perfect potion gets organic coconut oil from the island of pacific communities. This not only helps the island communities but also encourages local entrepreneurship. These are the intermediaries from which company sources most of its organic products to make a final thing for clients. They play a key role in its success. So in order to deal with this situation companies involved in producing such products should try to purchase their own lands to reduce the high cost of organic ingredients. Customer markets It is very essential to identify the changes in customer markets, their trends keep on fluctuating in the industry. People get more attracted to new things introduced by various competitor s. Therefore, it is essential for the company to have a wide network of retail services to cater a large market. Perfect potion has a wide network of retailing around 800 products. It has catered a large part of customer market. Though company always has a threat of better product and technology to be introduced in the market by other competitors, in this case it will increase cost of the company. In order to tackle with this situation company should be more innovative and should increase its market coverage in other regions, to overcome the uncertainty of changes in consumer market. The organization Organization can be a driving force in relation to the environment both internal and

Art Essay Example | Topics and Well Written Essays - 750 words

Art - Essay Example This paper talks about the some of the works of Auguste Rodin in regards to their detailed compositions like texture, color, form and matrial. Auguste Rodin Auguste Rodin was a french sculptor in the modern era who did not rebel on the past. Unlike other artists who deliberately changed their ways and created masterpieces that had undertones of mockery of the previous period, Rodin remained a traditional sculptor and took a craftsman-like approach to his works. He possesed a unique ability to work on complex materials. Most of his famous sculptures, departed from the traditional themes of mythology allegory, were criticized that made him become sensitive towards his critics. Nevertheess, he continued on his style, far away from the used-to-be themantic sculpture of the predominant figures of the past, and celebrated realism and individualism. As time went by, accompanied by a series of works, his stature in the artists' social ladder increased a few notches higher and gained increase d favour from the government and the artists community. Modernism 3 The Age of Bronze One of Rodin's works that troubled the critics and enticed them to lambast him for not having a conrete theme was The Age of Bronze. Speculations were in the air that Rodin intentionally scuplted his work without a theme. But due to its realistic and lively figure, it gained the attention of the many, which aslo fueled the critics to accuse him of surmoulage. He strongly denied the accusation and defended his work. He wrote and presented photographs of his model to newspapers to show how the sculpture differed. The Age of Bronze became one of Rodin's most famous works due to the controversy it brought to the eyes of the critics. The intricacy of the details of a man's nude body, held an unconventional pose, was sculpted well-enough for it to look alive. It takes a genuinely brillant artist to be able to sculpt a bronze material and still come up with a realistic form of a nude man. Tagged with perf ect lights and shadows, they made the sculpture an intriguing work of art, which eventually led to being bought by the state. The sculpture was purchased for 2,200 francs. Rodin drew inspiration for his first full-scale sculpture from Michelangelo's Dying Slave and was shown at the Paris Salon in 1877.(Rilke & Rodin, 2004, 27) St. John the Baptist Preaching St. John the Baptist Preaching is Rodin's second full-scale work and again a nude man. Due to the charge of surmoulage for his previous work, he made his second piece bigger than a life-size statue. The statues gives an appeal that he is walking towards the audience while both feet are on the ground. The odd positions of Rodin's works became his signature. The peculiar sense of movement of Rodin's model was captured in his product. Modernism 4 Rodin's interpretation of St. John the Baptist is a man preaching while walking. Although it may appear that the stance of the man is a bit odd, since both feet are on the ground, it depict s a walk of a determined man, emotionally firmed on his preaching. Rodin later explained how he came up with the two phases of a stride in order to suggest a movement. It is evident in the sculpture that the man, St. John, is preaching to a a group and his conviction is noticed. According to studies, the form of the model was excellently sculpted with an outstanding delivery of its message. The shadows on the ribs, the details on the facial expression and the

Synthesis, Characterization and Thermal Studies of NDPAH

Synthesis, Characterization and Thermal Studies of NDPAH Synthesis, characterization and Thermal Studies of a Bis {N- (2, 4- dinitro- phenyl) N- (3- phenyl- allylidene)- hydrazine} Uranyl (VI) nitrate  [UO2(NDPAH)2]2+ Shahriar Ghammamy, Sajjad Sedaghat Abstract Bis {N- (2, 4- dinitro- phenyl) N- (3- phenyl- allylidene)- hydrazine} abbreviated as NDPAH was synthesized and characterized. Bis {N- (2, 4- dinitro- phenyl) N- (3- phenyl- allylidene)- hydrazine} Uranyl (VI) nitrate prepared r Keywords: Bis {N- (2, 4- dinitro- phenyl) N- (3- phenyl- allylidene)- hydrazine} Uranyl (VI) nitrate, synthesis, thermal analysis, FT-IR and UV–Visible spectroscopy, Schiff bases. Introduction A Schiff base, named after Hugo Schiff, is a compound with a functional group that contains a carbonnitrogen double bond with the nitrogen atom connected to an aryl or alkyl group, not hydrogen. Complexes of uranyl with nitrogen ligand are of considerable interest due to broad spectrum of biological activities. Formation of transition metal complexes with ligands of uranyl family are important because this ligands connected with various modes to the electron-rich and electron-poor metals. uranyl containing ligands are known to form stable complexes with class b metal ions, such as gold (I). Nitrogen-containing ligands is an important factor in the development of coordination chemistry such as Schiff bases and their metal complexes. and biochemically relevant studies of metal complexes [1]. A group of nitrogen-containing ligands represent a wide range of biological activities and this class of ligands known as pyrimidine system. These groups are valuable ligands in chemistry and on th e other hand have a huge impact on biological properties. For example, a furopyrimidine ring according to the isoelectric contact with purine, is highly regarded. Other uses are as a pesticide and medicine such as antifolates, antimalarials, and antivirus and other hand, protects against radiation. Recently, it has been found that the fluoropyrimidines to prevent some of the vascular endothelial growth factor receptor 2 (VEGFR2) and high epidermal growth factor receptor (EGFR) is used However, many synthetic protocols that have been reported as long-term reactions or quick reactions suffer from defects and flaws. Requires a multi-step reaction, requires without water conditions, low efficiency, the use of metal constructions containing materials and special tools or starting substances are examples of these flaws. Therefore achieve new techniques and efficient for the preparation of furo (2, 3, d) derivatives of pyrimidine is still highly desirable [7] Pyrimidine represents a very i nteresting group of compounds, because these compounds are used extensively in phytosanitary, pharmaceutical, and analytical . On the other hand, industrial aspects of this class of compounds is considered. For example, these compounds are used as anti-bacterial and anti-fungal. [8]. This class of compounds also have biological activities [9–13]. The role of metal ions in biological processes of life has long been known and is highly regarded. Studying the properties of transition metal complexes with this class of biologically active ligands is very interesting. In this paper, the synthesis and characterization of a number of the ligands and uranyl complexes have been studied. In this work, we report the synthesis and structural studies of the ligand and complex isolated from the reactions of: Bis {N- (2, 4- dinitro- phenyl) N- (3- phenyl- allylidene)- hydrazine} Uranyl (VI) nitrate. Experimental Solvents were purified by standard methods. All reagents were supplied by Merck and were used without further purification. Melting point was measured in an Electro thermal 9200. The FT-IR spectra were recorded in the range 400–4000 cm-1 by KBr disk using a Bruker Tensor 27 M 420 FT-IR spectrophotometer. The UV–Vis spectra in CH3CN were recorded with a WPA bio Wave S2 100 spectrophotometer. Thermo gravimetric analyses were done on a Perkin Elmer TGA/DTA lab system l (Technology by SII) in nitrogen atmosphere with a heating rate of 20 ºC/min from 35- 700  ºC.  ¹ H and  ¹Ã‚ ³ C-NMR spectra were measured on a BRUKER DRX-500 AVANCE spectrometer at 500 MHz. Synthesis of the [UO2(NDPAH)2]2+: For synthesis of the [UO2(NDPAH)2]2+ to a magnetically stirred of ligand (0.88g, 2.8mmol) in acetonitrile(10ml) was added to uranyl (VI) nitrate (0.71g, 1.4 mmol) And the reaction is performed at room temperature. To ensure complex formation and precipitation of the complex. The solid complex obtained was filtered. And to remove material that did not participate in the reaction complex was washed with diethyl ether. Yield, 75%. Anal. Calcd of [UO2(NDPAH)2]2+; C; 20.14, H; 1.34, N; 6.26; found: C; 20.24, H. 1.41, N; 6.32. Mp: 290  °C.  ¹HNMR (DMSO): 7.4-7.9 (CH phenol), 8.5-8.8 (CH dinitrobenzen), 8.4 (CH azomethyne), 7.1 (CH), FT-IR (KBr, cm-1): 1133 s (ÃŽ ½ N-N), 1614 s (ÃŽ ½ C=N), 420 w (ÃŽ ½ U-N), 935 s (ÃŽ ½ O=U=O), UV-vis (DMSO): à ¯Ã‚ Ã‚ ¬max 260nm(ÃŽ µ 26000), 320nm(ÃŽ µ 15000), 413nm(ÃŽ µ 32000) (Figure 1-8). [UO2(NDPAH)2]2+ is soluble in chloroform, acetone, dichloro methane, DMSO and DMF and insoluble in water, hexane and diethyl ether and little soluble in methanol, Acetonitrile and ethanol. Figure 9, 10 shows Chemical structures of NDPAH and [UO2(NDPAH)2]2+. Analysis of NDPAH Ligand Anal: %68. Calcd of C15H12N4O4; C; 57.72, H; 3.84, N; 17.94; found: C; 57.81, H. 3.89, N; 17.99. Mp 254-256  °C,  ¹HNMR (DMSO): 7.3-7.7 (CH phenol), 7.8-8.5 (CH dinitrobenzen), 8.1 (CH azomethyne), 7.1 (CH), 9.1 (NH), FT-IR (KBr, cm-1): 1133 s (ÃŽ ½ N-N), 1613 s (ÃŽ ½ C=N), 3111 w (ÃŽ ½ NH). NDPAH is soluble in acetonitrile, acetone, chloroform, DMF, DMSO and diethyl ether insoluble in water, hexane, methanol and ethanol little soluble in dichloro methane. Results and discussion Preparation of Ligand and complex Compounds are quite stable and could be stored without any appreciable changes for long time. Compounds with multiple methods using FT-IR, UV-Visible and  ¹ H and  ¹Ã‚ ³ C-NMR spectra were identified. These compounds were evaluated for thermal analysis. In this paper, a new method for the synthesis of the Bis {N- (2, 4- dinitro- phenyl) N- (3- phenyl- allylidene)- hydrazine} Uranyl (VI) nitrate is presented . Following the single-step reaction between the UO2(NO3)2.6H2O and the NDPAH desired compound is obtained.This method has some advantages for the manufacture of complex. These include: there is no side products and does not require special conditions such as high pressure or high temperature, and that this reaction is a very fast reaction. The [UO2(NDPAH)2]2+ has 290 °C melting points respectively. It is soluble in chloroform, acetone, dichloro methane, DMSO and DMF and insoluble in water, hexane and diethyl ether and slightly soluble in methanol, acetonitrile, and ethanol . The spectral data of the complexes have good relationship with the literature data. The IR spectra of the Schiff base show characteristic bands due to ÃŽ ½(NH), ÃŽ ½(C=N) and ÃŽ ½(N-N), in the region 3111cm-1, (1613, 1133) cm-1 respectively. The strong band in the region 1613, 1133cm-1 in the IR spectra of the Schiff base are assigned to ÃŽ ½( C=N), ÃŽ ½( N-N) respectively. In the case of U(VI) complex we observed the following changes. The bands appeared around 1133, 1614, 420 and 935cm-1 due to ÃŽ ½ N-N, ÃŽ ½ C=N, ÃŽ ½ U-N and ÃŽ ½ O=U=O. Thermo gravimetric analyses The thermal properties of these compounds were investigated by thermo grams (TG, DTG and DTA). Figure 11 shows TGA and DTA curves for [UO2(NDPAH)2]2+. In the temperature range 200-305ËÅ ¡C, 57.9% weight losing was observed which was related to the loss of most parts of compound. In the temperature range from 360-500ËÅ ¡C, 20.6% weight reduction was found, which was related to the loss of a part of compound. Conclusion It is clear from the above discussion that [UO2(NDPAH)2]2+complex and NDPAH ligand offer a new outlook for chemotherapy. The results of antitumor activity show that the metal complexes exhibit antitumor properties and it is important to note that they show enhanced inhibitory activity compared to the parent ligand. The mechanism by which these complexes act as antitumor agents is apoptosis. It has also been proposed that concentration plays a vital role in increasing the degree of inhabitation. References [1] R.J. Vidmar, IEEE Trans. Plasma Sci. 21 (1992) 876-880. [2] A.S.N. Murthy, A.R. Reddy, Journal of Chemical Sciences. 90 (1981) 519-526. [3] V.N.K. Razakantoanina, P. Phung, Parasitology Research 86 (2000) 665-668. [4] R.E. Royer, D.L. Meck, Journal of Medicinal Chemistry. 38 (1995) 2427-2432. [5] M.R. Flack, P.R. G.yle, The Journal of Clinical Endocrinology Metabolism.  76 (1995) 1019-1024. [6] R. Baumgrass, M. Weiwad, Journal of Biological Chemistry. 276 (2001) 47914-47921. [7] M.B. Teimouri, R. Bazhrang, Bioorganic Medicinal Chemistry Letters.  16 (2006) 3697-3701. [8] M.B. Teimouri, Tetrahedron. 62 (2006)10849-10853. [9] J.M. Grevy, F. Tellez, Inorganica Chimica Acta. 339 (2002) 532-542. [10] A. Bernalte-Garc ´Ãƒâ€žÃ‚ ±a, F.J. Garc ´Ãƒâ€žÃ‚ ±a-Barros, Polyhedron. 18 (1999) 2907-2912. [11] K. Lemma, J. Berglund, Journal of Biological Inorganic Chemistry. 5 (2000) 300-306. [12] M.J.M. Campbell, Coordination Chemistry Reviews. 15 (1975) 279-319. [13] S. Padhy ´e, G.B. Kauffman, Coordination Chemistry Reviews. 63 (1985) 127-160. [14] B. Erwin, C. Omoshile, Journal of the Chemical Society Perkin Transactions. 2 (1995)1333-1338. [15] G.Zhao, H. Lin, Journal of Inorganic Biochemistry. 70 (1998) 219-226. Figure 1: FTIR spectrum of NDPAH (KBr Disk) Figure 2: FTIR spectrum of [UO2(NDPAH)2]2+ (KBr Disk) Figure 3: 1H- NMR spectrum of NDPAH Figure 4: 1H- NMR spectrum of [UO2(NDPAH)2]2+ Figure. 5. 13C- NMR spectrum of NDPAH Figure. 6. 13C- NMR spectrum of [UO2(NDPAH)2]2+ Figure 7: UV/ Vis spectrum of NDPAH (DMSO, 5Ãâ€"10-4 M) Figure 8: UV/ Vis spectrum of [UO2(NDPAH)2]2+ (DMSO, 5Ãâ€"10-4 M) Figure 9: Chemical structure of NDPAH Figure 10: Chemical structure of [UO2(NDPAH)2]2+ Figure 11: Thermal analysis data of [UO2(NDPAH)2]2+ Figure 1: FTIR spectrum of NDPAH (KBr Disk) Figure 2: FTIR spectrum of [UO2(NDPAH)2]2+ (KBr Disk) Figure 3: 1H- NMR spectrum of NDPAH Figure 4: 1H- NMR spectrum of [UO2(NDPAH)2]2+ Figure. 5. 13C- NMR spectrum of NDPAH Figure. 6. 13C- NMR spectrum of [UO2(NDPAH)2]2+ Figure 7: UV/ Vis spectrum of NDPAH (DMSO, 5Ãâ€"10-4 M) Figure 8: UV/ Vis spectrum of [UO2(NDPAH)2]2+ (DMSO, 5Ãâ€"10-4 M) Figure 9: Chemical structure of NDPAH Figure 10: Chemical structure of [UO2(NDPAH)2]2+ Figure 11: Thermal analysis data of [UO2(NDPAH)2]2+

Local Literature Essay

Follow-up or tracer studies have enjoyed popularity in LIS training needs/ assessment analyses over the past 20 years in Africa in studies by scholars such as Anadiran (1988) in Nigeria; Alemna (1991, 1999) and Kisie du (1993) in Ghana; Rosenberg (1989, 1994) in Kenya; Ocholla (2001 and 2005) and Stilwell (2004) in South Africa Rugambwa (1998) and Mammo (2007) in Ethiopia; Aina and Moahi (1999) in Botswana; and Lutwana and Kigongo – Bukenya (2004) in Uganda. Mammo (2007) conducted a study on the status of LIS education in Ethiopia and the perceptions of graduates on the LIS program me. The study revealed that in one university ,the LIS program me changed to Information Systems because of university-wide changes ,while in another university, the LIS curriculum remained the same. Graduates indicated that they were not satisfied with the LIS programme. 2 Lutwana and Kigongo-Bukenya (2004) conducted a study on the appropriateness of the EASLIS (East Africa School of Library and Information Science) curriculum to professional practice in Library and Information Science field in Uganda. The purpose of the study was to establish where graduates worked, what they did, and whether their education met employers’ expectations. It further identified areas of curriculum revision. The study revealed that most graduates were employed in academic institutions, government departments, banks and NGO’s libraries, where they performed various professional activities. The study also revealed that employers complained about the lack of practical skills among the graduates, citing specialization through electives as inadequate . Aina and Moahi (1999) conducted a tracer study of graduates from the Department of Library and Information Studies at the University of Botswana. The aim of the study was to determine the curriculum of the Department of LIS at the University of Botswana. The study revealed that the graduates were employed in traditional library settings. The study also found that their training was relevant to the tasks that they performed, although they advocated the strengthening of the information technology component of the curriculum . Kaijage (n. d. conducted a tracer study on the skills and knowledge of B. Com graduates of the University of Dares Salaam. The study concluded that the knowledge and skills that the graduates obtained from the university were relevant to their jobs. But it also suggested that changes should be made to the program me. There are also many other tracer studies conducted all over the Africa and the rest of the world. In South Africa, Stilwell (2004) conducted a survey of alumni perceptions of thepost graduate ILS (Information and Library Science program me at the University of Natal). Critical issues, such as balancing the human centre approach with IT, were identified. The findings of the study indicated that the program me achieved its outcomes because it prepared alumni well for the work place. Ocholla’s (2001) tracer study of LIS graduates from 1996 -1997 determined whether the skills and attitudes they gained during their training at the University of Zululand applied in their jobs. The results of the study indicate that graduates obtained sufficient knowledge from the degree program me . These examples indicate that tracer studies are generally conducted to find out about the fates of departmental graduates or alumni. They investigate where graduates are, whether they are employed, and employers’ perceptions about the skills and knowledge that LIS graduates have. They are also used to obtain feedback from employed alumni and employers on the relevance of the program me offered by different departments. Like most tracer studies, this study addresses the same questions: Are the graduates employable? Is the curriculum relevant? What are the perceptions of graduates and employers about the graduates’ skills, knowledge and education? Local literature At the Palanca literary awards dinner the other Saturday, Mrs. Sylvia Palanca Quirino invited the new Tourism Secretary, Ramon Jimenez Jr. , to be the guest speaker. Jimenez was responsible for coining the latest tourism come-on, â€Å"It’s More Fun in the Philippines. † He talked about literature and how it can help the tourism industry which, as we all know, has yet to be fully exploited. So many countries in our part of the world, particularly Thailand, have reaped millions from the flood of tourists visiting these countries. We get only a trickle, for though we have great possibilities, there is not enough global interest in our country and its attractions. Much of this is due to our own myopia, of our leaders who do not understand or realize the myriad possibilities here if we only know how to use them! Jimenez should produce long-range programs. This is one common fault of government; a new administration takes over and new policies are made no continuity is pursued. Will the slogan, â€Å"It’s More Fun in the Philippines† last only three years from now.? Will it be replaced when a new administration takes over? This is a minor point; will initiatives today be continued in the future? Does the present administration accept the past administration program enough to pursue its good aspects? Will our tourism executives use them? Just consider this: how many visitors go to England, to visit Stratford-on-Avon because they have enjoyed William Shakespeare’s plays. Those tourists clambering up the hills in Greece how many of them are there because they read the Homeric classics? And Spain, which reaps so much from the thousands upon thousands of visitors every year, how many visit that country because they have read Cervantes, and Hemingway’s novel, For Whom the Bell Tolls, and all those gory bullfight scenes in his fiction? Permit me to brag a bit. Once, I brought a busload of expats and some locals to the Ilokos because they wanted to see the setting of the Rosales saga. I was their tour guide. We went to my hometown, Rosales, and showed them two of the old houses which I used as models, and to that rundown barrio called Cabugawan where I was born, then on to Tayug where the Colorum rebelled in 1931, and to the Ilokos to see the old churches and finally to Cabugaw where the saga starts. And then one morning, more than a decade ago, a young man visited my bookshop. He was a schoolteacher in Holland; he had read Mass, the concluding novel in the Rosales saga which was published first in Dutch rather than in the English original. This was his first visit to Asia. Mass had appealed to him so much, he wanted to see its setting. I took him to Forbes Park first, then to Tondo, to Barrio Magsaysay and to Smokey Mountain which was still smoking then. Then we went to the university belt, to Recto and he saw all those young students milling about. And finally, that early evening we visited one of the massage parlors in Quezon City. Our National Hero, Jose Rizal he wrote the greatest Filipino novel why is there no literary tour based on his work and on his life? This literary tour will be more for Filipinos than for foreigners. It will impinge on our youth those virtues so terribly missing now the rectitude, the patriotism all the qualities which Rizal personified. Such a tour, led by a guide steeped in history, could start in the morning with a trip to Calamba, the Rizal house, the lake, and nearby Mt. Makiling. From there, back to Manila, to the Noli geography, the University of Santo Tomas, Binondo then Fort Santiago, the Luneta where Rizal was executed, and finally to Paco Cemetery where he was first buried. It could end with a view of the Manila sunset. Tourism for locals is growing it should be the way it is with Japan where the Japanese themselves are the best tourists in their own country. I told Jimenez to consider the movies. The Koreans are now producing epic historical movies, and those addictive telenovelas which have enthralled so many all over the world. My daughter-in-law, Lee Pai, who teaches history at the University of California at Santa Barbara happened to be visiting. She said those movies and telenovelas are scripted by Korea’s leading writers familiar with the literary classics of the West and East which explains the high quality of the telenovelas unlike the asinine and moronic serials produced by local TV. As evidenced by the Palanca awards, we are never short of literary talent. Why do our movie and TV people ignore them? Movie festivals are a great attraction in Europe and so are book fairs and literature meetings. Singapore has an international literary festival each year, India, too, and the annual Frankfurt Book Fair is one of the biggest attractions in this German city. Just concluded in Korea is the Annual PEN Congress an international meeting of writers. Writers attending this Congress will surely go home and write about Korea, further enlarging the global reach of that prosperous and booming country. Meanwhile, let me continue tossing encomiums at the Palancas for their perseverance, charity and goodwill in supporting the Awards for literature. I knew the founder, Carlos Palanca Jr. , personally he was very charming, debonair, with a wide circle of acquaintances in business and with the culturati. As far back as I can recall, it was the late NVM Gonzalez and Nick Joaquin who suggested to him the creation of the Awards to encourage literary excellence in the country. Sixty-two years three generations! I do not think such an effort has any equal in the region or in all of Asia. The vitality and continuing relevance of such effort requires organizational skills, massive expenditure and vision. It is a wonder to me why, up to now, this massive contribution of the Palancas to our culture and nation has not been publicly recognized. Filipino writers should be grateful to the children of Charlie Palanca who have not neglected their father’s vision. Sylvia Palanca Quirino leads them in plodding on. In the beginning, the awards were only for fiction and poetry in English and Tagalog they now include children’s stories, plays, novels, not just in these two languages but in Cebuano, Ilonggo and Ilokano. At the Awards dinner, Quirino also announced that the Awards will also recognize Filipino achievers. While the Palanca Awards promote creativity, it follows that media, particularly TV, can do so much by using the work of our best writers, as is done in Korea. Publishers can add to what the Palanca Awards have produced create literary sections in newspapers and magazines, publish those new and splendid works. May I also now suggest to Mrs. Socorro Ramos that her National Book Stores all over the country should exhibit in their show windows Filipino books, both fiction and non-fiction? They deserve exposure, a much wider audience. Do all these not because it is patriotic but because these good writers deserve a wider readership in their own country.